Lawrence Livermore National Laboratory



Alan DeHope

Research Staff
Materials Science Division


 +1 925-423-1018


DegreeDiscipline/InstitutionYear
Ph.D.
University of California at Riverside
2010
M.S.
University of California at Riverside
2006
B.S.
University of California at Riverside
2005

Research Interests

  • Energetic materials synthesis, scale-up, and formulation
  • Isolation of reactive intermediates, main-group and organometallic chemistry
  • Nitration and oxidation methodologies

Selected (Recent) Publications

New polynitro alkylamino furazans DeHope, Alan; Pagoria, Philip F.; Parrish, Damon. New Trends in Research of Energetic Materials, Proceedings of the 16th Seminar, Pardubice, Czech Republic 2013, Pt. 1, 129-135

"Green" energetic materials synthesis at LLNL Pagoria, Philip; DeHope, Alan; Zhang, Mao Xi; Lee, Gregory; Mitchell, Alexander; Leonard, Philip. New Trends in Research of Energetic Materials, Proceedings of the 15th Seminar, Pardubice, Czech Republic 2012, Pt. 1, 55-65.

Grubbs and Hoveyda-type ruthenium complexes bearing a cyclic bent-allene DeHope, Alan; Donnadieu, Bruno; Bertrand, Guy. Journal of Organometallic Chemistry 2011, 696, 2899-2903.

A persistent (amino)(ferrocenyl)carbene DeHope, Alan; Mendoza-Espinosa, Daniel; Donnadieu, Bruno; Betrand, Guy. New Journal of Chemistry 2011, 35, 2037-2042

Exocyclic Delocalization at the Expense of Aromaticity in 3,5-bis (π-Donor) Substituted Pyrazolium Ions and Corresponding Cyclic Bent Allenes Fernandez, I.; Dyker, C. A.; DeHope, A.; Donnadieu, B.; Frenking, G.; Bertrand, G. Journal of the American Chemical Society 2009, 131, 11875-11881.

Recently Reported Crystalline Isothiazole Carbenes: Myth or Reality DeHope, Alan; Lavallo, Vincent; Donnadieu, Bruno; Schoeller, Wolfgang W.: Bertrand, Guy. Angewandte Chemie, International Edition 2007, 46, 6922-6925.

A rigid cyclic (alkyl) (amino) carbene ligand leads to isolation of low-coordinate transition-metal complexes Lavallo, Vincent; Canac, Yves; DeHope, Alan; Donnadieu, Bruno; Bertrand, Guy. Angewandte Chemie, International Edition 2005, 44, 7236-7239.

Presentations

16th International Seminar "New Trends in Research of Energetic Materials" New Polynitro alkylamino furazans. 10th-12th April 2013, Pardubice, CZ

Gordon Conference on Energetic Materials Synthesis of 1,2,4-oxadiazole derivatives as energetic compounds. 17th-22nd June 2012, West Dover, VT

8th Primary Explosives Workshop Energetic materials synthesis at LLNL. 8th-9th May 2012, Chandler, AZ

59th Joint Army-Navy-NASA-Air Force (JANNAF) Propulsion Meeting Synthetic efforts towards high-nitrogen content 1,2,4-oxadiazoles. 30th April – 4th May 2012, San Antonio, TX


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